A most excellent book for learning to program in C# is 'Windows Forms Programming with C#' by Erik Brown

http://www.amazon.com/exec/obidos/tg/detail/-/1930110286/qid=1082326587/sr=8-1/ref=sr_8_xs_ap_i1_xgl14/104-6061999-7028710?v=glance&s=books&n=507846