I just bought this fantastic book

Build Your Own ASP.NET Website Using C# & VB.NET By Zak Ruvalcaba

http://www.sitepoint.com/books/aspnet1/

I am about half way through it and I have learned quite a bit so far.

Not sure? Read the first 4 chapters:
http://www.sitepoint.com/books/aspnet1/aspnet-sample.pdf

Enjoy!

Chris