Thanks a Lot Dude Smiley

1.

Open the "SQL server Configuration Manager", right-click the line "Protocols for MICROSOFT##SSEE" and choose "Properties". The "hide instance" field is set to "yes", put "no" instead, validate, and restart the microsoft##ssee service...

2. 
SQL Server Configuration Manager -->  SQL Native Client Configuration  ---> Aliases  --->  Right click on Alias name:  <servername>\Microsoft##SSEE --->  properties  --->   Change the Alias Name from <servername>\Microsoft##SSEE to <servername>\##SSEE.  

Worked & my Central Administration is working fine....
 
- PrashanthSpark
 Sharepoint Architect
 INDIA