no problem

most people here on channel9 and the msdn forums are happy to help out new VS users

(some arent but never mind those)
ive only really used netbeans for ruby development so im not that familiar wit the java experience
you can invoke intellisense by hitting ctl-space (or possebly alt or * space in the default key mapping) to show members that starts with whatever you've written
check out the edit > intellisense menu. you can change those hotkeys in the tools > options >environment >keyboard options

VS doesnt show you all the docs at once like netbeans, instead, the docs for the method is shown if the cursor is over the method, and each paramater if the cursor is on the parameter.
the parameters arent shown while the cursor is on the method body because the diffrent overloads may have diffrent arguments meaning diffrent things. experiment with typing . after a a string for instance and try starting to type the parameters to a method and see what shows up

if you want something like the navigator window. you can use the two drop down menus at the top of the ide.
the right one shows the the types in the current file (c# can have multiple types in a file) and the left one shows the members in the selected type
also, you can check out the object browser (view > object browser) from there you can browse all the namespaces referenced in your project and also view the comments for classes and methods
i also have a java background from my school days and ive been a c# dev all my prof life. you'll find that c# is more of a superset of java when it comes to functionality with events and delegates (although events are actually delegates) and linq and attributes and various other things
you should note though that c# is not a native language. c# is compiled to byecode and then jitted to native code at runtime
