Alright, @magicalclick and @Sven, I've just downloaded the separate SkyDrive app for the desktop version of Windows 8. Seems to work fine.

I wonder though, with SkyDrive on the Metro side and on the desktop side, how do they do together? For example, yesterday when I downloaded the SkyDrive app for the desktop I went through the process of setting up what folders I wanted synced with the SkyDrive cloud and all, and I got to wondering, did I make the same choices when I did this for the Metro version?