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View Thread: How do I get a Windows XP Mode VM to join our AD?
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    Assuming you've got networking working on it properly, you just boot the VM in VirtualPC and domain join it as per usual.

    I'm not sure whether it's officially a "supported scenario" or not though, as various domain policies may well break some of the XP Mode functionality. I think that MED-V was the preferred route for scenarios that needed domain-joined XP VMs (it's been a while since I looked into it).